Trying to match two shots, just for giggles
 

I've been trying to get two shots to match, the lighting wasn't altered much, but the angle was. I'm trying to get the second shot to look like the first, I want the hair black and the skin white. So far, can't get the brown out of her skin and hair. I used the Glow fx in both shots.
Vegas 9.0a, 720p m2t timeline.

Hi Brian. Here's a quick attempt using Vegas 7. The background has come out stronger than I would like, but this was to prevent the girl's face from blending too much into the background. If I was doing this for real, I would probably use a mask to improve on this.

Richard

Here's the veg file in case you are interested.

Richard

Looks better than mine! It's tough to make her hair and skin contrast because they're both brown.